A tandem organosolv pulping and Pd-catalysed transfer hydrogenolysis depolymerisation and deoxygenation has been developed. The tandem process generated 2-methoxy-4-(prop-1-enyl)phenol in 23% yield (92% theoretical monomer yield) starting from pine wood and 2,6-dimethoxy-4-(prop-1-enyl)phenol in 49% yield (92% theoretical monomer yield) starting from birch wood. Only endogenous hydrogen from wo...

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Benzene was hydroxylated with hydrogen peroxide (H2O2) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperature, phenol was further hydroxylated with H2O2 by catalysis of copper complexes to yield p-benzoquinone. The kinetic study revealed that the rate was proportional to concentrations of benzene and H2O2, but to the square root of co...

2,6-Di-tert-butyl-4-nonylphenol(DTBNP) was synthesized from 4-n-nonyl phenol and isobutylene, etc. using self-made composite super acid as catalyst. The appropriate technology conditions are as follows: reaction temperature is 60-80 , reaction time is 4h, n 4-n-nonyl phenol : n Isobutylene = 1: 2 and the amount of catalysts is 0.019% of the quantity of 4-n-nonyl phenol reactant, the yield can r...

On the biotransformation of phenol and monofluorophenols by the cultured cells of Eucalyptus perriniana, phenyl and fluorophenyl b-D-glucosides were isolated after a 1-h incubation. Especially, the yield of 2-fluorophenol is higher than those of the other substrates, i.e., phenol, 3and 4-fluorophenols. These results indicated that E. perriniana cells selectively glycosylate the hydroxyl group o...

In this study the effect of four levels of nitrogen fertilizer (0, 50, 100, 150) kg/ha and four levels of super phosphate triple (0, 50, 100, 150) kg/ha were investigated on Rubia Inctorum L. (madder) under salinity stress. A factorial experiment was carried out in a research farm in Roaddasht, Isfahan based on complete randomized blocks with three replications. The results of the variance anal...

The brown-rotted wood was liquefied in phenol with phosphoric acid as catalyst and the resulting liquefied products were condensed with formaldehyde to yield novolak liquefied wood-based phenol formaldehyde resin (LWPF). The results showed that brown-rotted wood could be more easily liquefied than sound wood in phenol. The residue content of liquefied wood decreased continually with the progres...

Black liquor alkaline lignin and magnesium lignosulfonate were liquefied at 320 C. The antioxidant abilities of the liquefaction products were compared with the raw materials. Results showed that the total phenol content and unit antioxidant power of both alkaline lignin liquefaction products (ALLP) and magnesium lignosulfonate liquefaction products (MLLP) were improved, and ALLP had a larger i...

The title compound, C(2)H(8)N(+)·C(6)H(4)NO(3) (-)·C(6)H(5)NO(3), was synthesized from dimethyl-amine and 4-nitro-phenol in an overall yield of 85%. The dihdral angles between the nphenyl rings and their attached nitro groups are 5.7 (6) and 2.5 (7)°. In the crystal, there are strong hydrogen bonds between the ammonium group and the nitro-phenol and nitro-phenolate O atoms, and between the nitr...

vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...